/^((([a-z]|\d|[!#\$%&'\*\+\-\/=\?\^_`{\|}~]|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])+(\.([a-z]|\d|[!#\$%&'\*\+\-\/=\?\^_`{\|}~]|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])+)*)|((\x22)((((\x20|\x09)*(\x0d\x0a))?(\x20|\x09)+)?(([\x01-\x08\x0b\x0c\x0e-\x1f\x7f]|\x21|[\x23-\x5b]|[\x5d-\x7e]|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])|(\\([\x01-\x09\x0b\x0c\x0d-\x7f]|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF]))))*(((\x20|\x09)*(\x0d\x0a))?(\x20|\x09)+)?(\x22)))@((([a-z]|\d|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])|(([a-z]|\d|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])([a-z]|\d|-|\.|_|~|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])*([a-z]|\d|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])))\.)+(([a-z]|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])|(([a-z]|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])([a-z]|\d|-|\.|_|~|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])*([a-z]|[\u00A0-\uD7FF\uF900-\uFDCF\uFDF0-\uFFEF])))\.?$/i

该正则由Scott Gonzalez提供，应该没有再完整的了。。。

用RegexBuddy转化为PHP版本的：

/^((([a-z]|\d|[!#$%&\'*+\-\/=?\^_`{|}~]|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])+(\.([a-z]|\d|[!#$%&\'*+\-\/=?\^_`{|}~]|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])+)*)|((\x22)((((\x20|\x09)*(\x0d\x0a))?(\x20|\x09)+)?(([\x01-\x08\x0b\x0c\x0e-\x1f\x7f]|\x21|[\x23-\x5b]|[\x5d-\x7e]|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])|(\\\\([\x01-\x09\x0b\x0c\x0d-\x7f]|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}]))))*(((\x20|\x09)*(\x0d\x0a))?(\x20|\x09)+)?(\x22)))@((([a-z]|\d|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])|(([a-z]|\d|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])([a-z]|\d|-|\.|_|~|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])*([a-z]|\d|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])))\.)+(([a-z]|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])|(([a-z]|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])([a-z]|\d|-|\.|_|~|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])*([a-z]|[\x{00A0}-\x{D7FF}\x{F900}-\x{FDCF}\x{FDF0}-\x{FFEF}])))\.?$/iu